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在国内,火花放电原子发射光谱分析广泛使用类型标准化进行方法校正。在国外,标准和文献中鲜见使用此方法的相关论述。类型标准化主要采用平移校正和转动校正两种方式,哪种方式更加合理也鲜见报道。国外设备类型标准化的默认设置优先采用转动校正方式,相关国内标准对最优校正方式的规定尚不明确,此默认设置的合理性有待探讨。实验选用低合金钢20CrNi2Mo、R407标准样品和不锈钢317L、0Cr18Ni9标准样品,引用国内相关标准,以正确度临界差为评判依据,模拟类型标准化样品和待测样品“十分接近”和“接近”两种情况下平移校正和转动校正的数据正确度。经数据统计分析,平移校正分析结果均满足要求,转动校正结果在“接近”情况下部分元素不满足要求。结合相关国家标准中元素含量范围和精密度数据进行分析,通过计算允许最大偏倚量并制作曲线图方式展开分析,得出如下结论:在满足文中类型标准化控制要点前提下,分析设置更适合于采用平移校正方式。 相似文献
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东北亚地区至少发育9个大型草原石林,属花岗岩石林的一种,是东北亚早白垩世巨量伸展和第四系冰川、风化作用的共同产物,主要特点是发育密集的近水平节理。本文通过整理岩浆岩专题填图和构造研究发现,这些石林的主体是早白垩世东北亚地区巨量伸展过程中形成众多的不对称花岗岩穹隆或同减薄岩体,岩体边部发育韧性剪切带,核部发布近水平岩浆流动面理,伸展和岩浆多期侵位导致与成矿密切相关的岩浆热液大量上涌,岩体抬升至地表,沿岩浆面理发育密集的近水平节理和部分垂直节理,后期沿这些构造面理发生的物理风化和化学作用(包括风蚀、冰川以及盐风化等)造就了千奇百怪的形态。草原石林是花岗岩地貌中的“另类”,不仅具有指示东北亚地区花岗岩形成时代(早白垩世)的特点,也是寻找晚中生代中国北方大规模成矿的良好标志体,而且风化形成的千姿百态的景色极具观赏价值,可以作为整个蒙古草原地区和大兴安岭南段地区特色的地学科普和生态旅游资源。 相似文献
24.
采用超高效液相色谱⁃四极杆⁃飞行时间高分辨质谱(UPLC⁃Q⁃TOF)对4类不同类型的含聚对苯二甲酸乙二醇酯(PET)材质的食品接触材料在4 %乙酸和50 %乙醇模拟物中的迁移出的非挥发性未知物进行筛查解析。结果表明,产品在4 %乙酸模拟物的迁移风险远小于50 %乙醇模拟物,主要迁移物质为聚合单体形成的寡聚物,抗氧剂、润滑剂、胶黏剂等加工助剂以及生产加工、迁移过程中形成的非有意添加物(NIAS)物质;纯PET材质的产品迁移物质较少,多层复合材料迁移物质较多。复合材质的产品中,PET材质可能在生产时添加了己二酸、癸二酸、新戊二醇等物质,进行了改性处理;此外,部分迁移物质会与模拟物中的乙醇发生反应,生成新的NIAS物质。 相似文献
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Yang Lu Panpan Li Wenqing Xie Yongmin Duan Xiyang Wang Shiqing Xu Junjie Zhang 《Journal of the European Ceramic Society》2021,41(6):3635-3642
Halide perovskite glass-ceramic has recently moved into the center of the attention of perovskite research due to their potential for temperature sensing. However, quantum dots glass-ceramic with excellent luminescence performance still needs to be combined with rare-earth (RE) ions to accurately measure temperature. In this work, a novel non-RE doped dual-emission (460 nm and 512 nm) CsPbBr3 quantum dots was obtained in telluride glass via the friction crystallization method, where 512 nm was derived from intrinsic luminescence of quantum dots, and 460 nm was originated from thermally induced bromine vacancy, which can be used for temperature sensing. Fluorescence intensity ratio results indicate that the relative sensitivity of dual-emission could reach 5.6 % K?1 at 323 K. The discovery of non-RE doped CsPbBr3 QDs glass-ceramic with negative thermal quenching uncovers a new optional sensing glass material that surpass traditional RE-doped QDs glass by their tunability and sensitivity. 相似文献
27.
Yingfeng XU Youiun HU Xiaodong ZHANG Xingyuan XU Lei YE Xiaotao XIAO Zhen ZHENG 《等离子体科学和技术》2021,23(9):95102-23
NBI fast ion losses in the presence of the toroidal field ripple on EAST have been investigated by using the orbit code GYCAVA and the NBI code TGCO. The ripple effect was included in the upgraded version of the GYCAVA code. It is found that loss regions of NBI fast ions are mainly on the low field side near the edge in the presence of ripple. For co-current NBIs, the synergy effect of ripple and Coulomb collision on fast ion losses is dominant, and fast trapped ions located on the low field side are easily lost. The ripple well loss and the ripple stochastic loss of fast ions have been identified from the heat loads of co-current NBI fast ions. The ripple stochastic loss and the collisioninduced loss are much larger than the ripple well loss. Heat loads of lost fast ions are mainly localized on the right side of the radio frequency wave antennas from the inside view toward the first wall. For counter-current NBIs, the first orbit loss due to the magnetic drift is the dominant loss channel. In addition, fast ion loss fraction with ripple and collision for each NBI linearly increases with the effective charge number, which is related to the pitch angle scattering effect. 相似文献
28.
Huimin Tang Zhiwei Peng Foquan Gu Lei Yang Weiguang Tian Qiang Zhong Mingjun Rao Guanghui Li Tao Jiang 《Ceramics International》2021,47(8):10809-10818
The chromium-promoted preparation of forsterite refractory materials from ferronickel slag was investigated by microwave sintering of the slag with the additions of sintered magnesia and 0–10 wt% chromium oxide (Cr2O3). The thermodynamic calculations revealed that the addition of Cr2O3 can promote the formations of spinel and liquid phase and maintain high content of forsterite below 1500 °C. The experimental results showed that there existed a stronger promoting effect of Cr2O3 additive on the properties of refractory materials in the microwave field than that in conventional sintering. It was attributed to the preferential formation and growth of spinel with stronger microwave absorption than other phases (e.g., enstatite), the existence of more forsterite, and the enhanced densification in association with the presence of more liquid phase at the same temperature. By microwave sintering of the mixture of ferronickel slag, 25 wt% sintered magnesia, and 4 wt% Cr2O3 at 1350 °C for 20 min, a superior refractory material with refractoriness of 1801 °C, thermal shock resistance of 6 times, bulk density of 2.97 g/cm3, apparent porosity of 1.4%, and compressive strength of 197 MPa was obtained. Compared with that prepared by conventional sintering at 1350 °C for 2 h, the refractoriness and thermal shock resistance were increased by 175 °C and 100%, respectively. The present study provided a novel method for preparing high-quality refractory materials from ferronickel slag and relevant industrial wastes. 相似文献
29.
Hengtao Wang Hui Chen Weicheng Xie Hanjian Lai Tingxing Zhao Yulin Zhu Lin Chen Chunxian Ke Nan Zheng Feng He 《Advanced functional materials》2021,31(26):2100877
The design of polymer acceptors plays an essential role in the performance of all-polymer solar cells. Recently, the strategy of polymerized small molecules has achieved great success, but most polymers are synthesized from the mixed monomers, which seriously affects batch-to-batch reproducibility. Here, a method to separate γ-Br-IC or δ-Br-IC in gram scale and apply the strategy of monomer configurational control in which two isomeric polymeric acceptors (PBTIC-γ-2F2T and PBTIC-δ-2F2T) are produced is reported. As a comparison, PBTIC-m-2F2T from the mixed monomers is also synthesized. The γ-position based polymer (PBTIC-γ-2F2T) shows good solubility and achieves the best power conversion efficiency of 14.34% with a high open-circuit voltage of 0.95 V when blended with PM6, which is among the highest values recorded to date, while the δ-position based isomer (PBTIC-δ-2F2T) is insoluble and cannot be processed after parallel polymerization. The mixed-isomers based polymer, PBTIC-m-2F2T, shows better processing capability but has a low efficiency of 3.26%. Further investigation shows that precise control of configuration helps to improve the regularity of the polymer chain and reduce the π–π stacking distance. These results demonstrate that the configurational control affords a promising strategy to achieve high-performance polymer acceptors. 相似文献
30.
Fenglin Hua Hong Wei Fupeng Ren Mingming Wang Li Li Bolin Lv Huan Wang Zhiwang Yang Ziqiang Lei 《火与材料》2022,46(1):95-106
A novel ternary hybrid flame retardant named P-g-C3N4@PGS-Ti was prepared through step-by-step method. First, titanium dioxide was loaded on PGS to make PGS-Ti (where PGS = palygorskite), and then, PGS-Ti was decorated by phosphor-doped g-C3N4 (abbreviated as P-g-C3N4) to prepare a ternary flame retardant of P-g-C3N4@PGS-Ti. It showed that P-g-C3N4@PGS-Ti could efficiently improve the flame retardancy of epoxy resins (EP). The structure and the morphology of P-C3N4@PGS-Ti were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, scaanning electron microscopy and hermogravimetric analysis (TGA). The flame retardancy and the burning behavior of 5 wt% P-g-C3N4@PGS-Ti composited EP were well investigated through TGA, limiting oxygen index (LOI), cone calorimeter test (CCT) and vertical burning test (UL-94 standard). It was found that the peak heat releasing (pk-HRR) of the EP/P-g-C3N4@PGS-Ti composite reduced 36% (from 1459 to 852 kW/m2) with the addition of 5 wt% of P-g-C3N4@PGS-Ti flame retardant to the matrix of EP. The combustion residue analysis showed that the EP/P-g-C3N4@PGS-Ti composite gained the most continuous and firmest char yield due to the synergistic effect of PGS, TiO2 and the introducing of P element. The mechanism proved that the combination of gas phase and condensed phase flame-retardant processes were well coordinated to improve the fire retardancy for EP. We tested and studied the mechanical properties of EP/P-g-C3N4@PGS-Ti composites. Only 2.4% decreasing of flexural strength and 23.5% decreasing of impact strength in EP/P-g-C3N4@PGS-Ti composites compared to pure EP, respectively. But according to the test results of EP/P-g-C3N4@PGS-Ti composite material and the control sample in the system, EP/P-g-C3N4@PGS-Ti composite material had the highest flexural modulus and impact strength. 相似文献